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101.
Solar System Research - The ionization-type cosmic dust detector METEOR-L is being developed for the lunar orbiter Luna-26 and is designed to study the distribution of meteoric bodies in space by...  相似文献   
102.
The Shenandoah Watershed Study (established in 1979) and the Virginia Trout Stream Sensitivity Study (established in 1987) serve to increase understanding of hydrological and biogeochemical changes in western Virginia mountain streams that occur in response to acidic deposition and other ecosystem stressors. The SWAS-VTSSS program has evolved over its 40+ year history to consist of a temporally robust and spatially stratified monitoring framework. Currently stream water is sampled for water quality bi-hourly during high-flow events at three sites and weekly at four sites within Shenandoah National Park (SHEN), and quarterly at 72 sites and on an approximately decadal frequency at ~450 sites within the wider western Virginia Appalachian region. Stream water is evaluated for pH, acid neutralizing capacity (ANC), base cations (calcium, magnesium, sodium and potassium ion), acid anions (sulphate, nitrate and chloride), silica, ammonium, and conductivity with a subset of samples evaluated for monomeric aluminium and dissolved organic carbon. Hourly stream discharge (four sites) and in-situ measurements of conductivity, water and air temperature (three sites) are also measured within SHEN. Here we provide an overview and timeline of the SWAS-VTSSS stream water monitoring program, summarize the field and laboratory methods, describe the water chemistry and hydrologic data sets, and document major watershed disturbances that have occurred during the program history. Website links and instructions are provided to access the stream chemistry and time-series monitoring data in open-access federal databases. The purpose of this publication is to promote awareness of these unique, long-term data sets for wider use in catchment studies. The water chemistry and hydrologic data can be used to investigate a wide range of biogeochemical research questions and provide key inputs for models of these headwater stream ecosystems. SWAS-VTSSS is an ongoing program and quality assured data sets are uploaded to the databases annually.  相似文献   
103.
Three pre-mixed powdered clay-based (earthen) plasters produced in Europe and specifically designed for wall undercoating were analyzed in this paper. These materials are commercially available and successfully employed in green building practices all over the world. Their compositional and textural characteristics, as well as plastic behaviour were investigated through a multi-analytical approach: X-ray powder diffraction (XRPD), polarized light microscopy (PLM), X-ray fluorescence spectrometry (XRFS), scanning electron microscopy equipped with an energy dispersive spectrometer (SEM-EDS), mercury intrusion porosimetry (MIP), grain-size distribution (GSD) and semi-empirical tests (Atterberg Limits, Linear Shrinkage). In addition, a natural earth (a terra rossa red soil sampled in north-western Sicily), theoretically appropriate for the production of earthen plaster, was subjected to the same analytical routine and compared with the three commercially available pre-mixed products. The achieved results allowed to individuate the compositional and textural features that primarily influence the performances of the studied earthen plasters. The obtained data are expected to be also useful in directing the selection of raw materials for local manufacture of specifically designed innovative products.  相似文献   
104.
105.
Late Quaternary (MIS 3 to Recent) oceanographic evolution of the Basque shelf has been analysed for the first time based on the sedimentological analysis of three cores obtained from the middle and outer shelves. The cores are located in two interfluves separated by the San Sebastian canyon. The variability of the percentage of the planktonic foraminifera species Neogloboquadrina pachyderma sin. and of δ18Obull allowed us to identify the influence of colder and warmer waters in the Basque shelf during the late Quaternary. From 56 cal. ka BP to the end of the Last Glacial Maximum (19 cal. ka BP) the sedimentary record shows a decreasing trend in the mean grain size that correlates with the eustatic sea‐level fall. The last Deglaciation (19–11.5 cal. ka BP) is characterized by a sea‐level rise that produced an important hiatus in the western outer shelf. During the Holocene, the middle and outer shelves present different behaviours. From 11.5 to 6.7 cal. ka BP, in the outer shelf the sea‐level rise that started during the Deglaciation produced a hiatus, whereas in the middle shelf the sedimentary succession records the presence of warm to temperate waters. Between 6.7–4.9 cal. ka BP, the entrance of cold surface water‐masses that only affected the middle shelf has been identified, and temperate to warm waters occurred in the outer shelf. The cold surface water‐masses retreated during 4.9–4.3 cal. ka BP in the middle shelf. Finally, from 4.3 cal. ka BP to Recent, the middle shelf registers a hiatus due to sea‐level stabilization after a generalized transgression, synchronous to a decrease in the energy of the water‐masses in the outer shelf. In conclusion, the environmental changes detected in the Basque shelf are attributed to both regional and eustatic sea‐level changes.  相似文献   
106.
Coexisting garnet blueschist and eclogite from the Chinese South Tianshan high‐pressure (HP)–ultrahigh‐pressure (UHP) belt consist of similar mineral assemblages involving garnet, omphacite, glaucophane, epidote, phengite, rutile/sphene, quartz and hornblendic amphibole with or without paragonite. Eclogite assemblages generally contain omphacite >50 vol.% and a small amount of glaucophane (<5 vol.%), whereas blueschist assemblages have glaucophane over 30 vol.% with a small amount of omphacite which is even absent in the matrix. The coexisting blueschist and eclogite show dramatic differences in the bulk‐rock compositions with higher X(CaO) [=CaO/(CaO + MgO + FeOtotal + MnO + Na2O)] (0.33–0.48) and lower A/CNK [=Al2O3/(CaO + Na2O + K2O)] (0.35–0.56) in eclogite, but with lower X(CaO) (0.09–0.30) and higher A/CNK (0.65–1.28) in garnet blueschist. Garnet in both types of rocks has similar compositions and exhibits core–rim zoning with increasing grossular and pyrope contents. Petrographic observations and phase equilibria modelling with pseudosections calculated using thermocalc in the NCKMnFMASHO system for the coexisting garnet blueschist and eclogite samples suggest that the two rock types share similar P–T evolutional histories involving a decompression with heating from the Pmax to the Tmax stage and a post‐Tmax decompression with slightly cooling stage, and similar P–T conditions at the Tmax stage. The post‐Tmax decompression is responsible for lawsonite decomposition, which results in epidote growth, glaucophane increase and omphacite decrease in the blueschist, or in an overprinting of the eclogitic assemblage by a blueschist assemblage. Calculated P–X(CaO), P–A/CNK and P–X(CO2) pseudosections indicate that blueschist assemblages are favoured in rocks with lower X(CaO) (<0.28) and higher A/CNK (>0.75) or fluid composition with higher X(CO2) (>0.15), but eclogite assemblages preferentially occur in rocks with higher X(CaO) and lower A/CNK or fluid composition with lower X(CO2). Moreover, phase modelling suggests that the coexistence of blueschist and eclogite depends substantially on P–T conditions, which would commonly occur in medium temperatures of 500–590 °C under pressures of ~17–22 kbar. The modelling results are in good accordance with the measured bulk‐rock compositions and modelled temperature results of the coexisting garnet blueschist and eclogite from the South Tianshan HP–UHP belt.  相似文献   
107.
In the classical view of metamorphic microstructures, fast viscous relaxation (and so constant pressure) is assumed, with diffusion being the limiting factor in equilibration. This contribution is focused on the only other possible scenario – fast diffusion and slow viscous relaxation – and brings an alternative interpretation of microstructures typical of high‐grade metamorphic rocks. In contrast to the pressure vessel mechanical model applied to pressure variation associated with coesite inclusions in various host minerals, a multi‐anvil mechanical model is proposed in which strong single crystals and weak grain boundaries can maintain pressure variation at geological time‐scales in a polycrystalline material. In such a mechanical context, exsolution lamellae in feldspar are used to show that feldspar can sustain large differential stresses (>10 kbar) at geological time‐scales. Furthermore, it is argued that the existence of grain‐scale pressure gradients combined with diffusional equilibrium may explain chemical zoning preserved in reaction rims. Assuming zero net flux across the microstructure, an equilibrium thermodynamic method is introduced for inferring pressure variation corresponding to the chemical zoning. This new barometric method is applied to plagioclase rims around kyanite in felsic granulite (Bohemian Massif, Czech Republic), yielding a grain‐scale pressure variation of 8 kbar. In this approach, kinetic factors are not invoked to account for mineral composition zoning preserved in rocks metamorphosed at high grade.  相似文献   
108.
Palaeoproterozoic metasedimentary migmatite reflects the highest temperature parts of a regional aureole at Mt Stafford, central Australia, comprising rocks that experienced 500–800 °C at ≈3 kbar. Whole‐rock major element concentrations are correlated with Zr content, psammitic compositions having nearly twice the Zr content of pelitic compositions. Zirconium is concentrated in mesosome compared with leucosome. Zircon is largely detrital, mostly lacking any overgrowth contemporary with migmatite formation. Comparatively small proportions of micro‐zircon (<10 μm) in sub‐solidus rocks are mostly hosted by quartz and plagioclase. Much higher proportions (three to five times) of micro‐zircon in migmatite are hosted by prograde K‐feldspar, cordierite and biotite. TX and PT NCKFMASHTZr pseudosections constructed using thermocalc model the distribution of Zr between solid and silicate liquid phases. Half of the detrital zircon (~100 ppm Zr) is predicted to be dissolved into silicate liquid at ≈800 °C and all dissolved by 850 °C, if all zircon is involved in the equilibration volume. Melt segregation at relatively low temperature is predicted to enrich the residuum in Zr, consistent with the observed distribution of Zr between mesosome and leucosome. The limited development of metamorphic zircon rims or overgrowths at Mt Stafford is explained by three concurrent processes: (i) Zr liberated during prograde metamorphism formed micro‐zircon, rather than following the prediction that Zr will partition into silicate liquid; (ii) some detrital zircon was probably armoured by other rock‐forming minerals, reducing Zr content in the effective bulk rock composition; and (iii) small proportions of melt loss during migmatization removed Zr that otherwise would have been available to form metamorphic rims.  相似文献   
109.
Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Aldithionate, Aloxalate, Fedithionate, and Feoxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
110.
Large water‐sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre‐impoundment and post‐impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20th century, carcass waste, stock‐yard manure, and untreated human wastes measurably increased ammonia and organic‐nitrogen concentrations during low flows. Average total‐nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate‐organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended‐sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post‐impoundment period. If strategies to decrease total‐nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation of wetlands along the Missouri River could be part of such a nitrate‐reduction strategy. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   
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